vorpX tries to attach itself to every DX9-DX11 game, which works in most cases, even if a game is not directly supported. Unless there is a profile for a game there is no guarantee though, since some games need special treatment.
If an usupported game doesn’t hook with the auto detection, you can try to create a vorpX desktop shortcut (right click the vorpX tray icon, select “Create Desktop Shortcut”). There is still no guarantee for unsupported games, but the chances are higher this way for games that aren’t detected otherwise.
Hope this helps.