Disabling FluidSync on the display page of the vorpX ingame menu will unlock the frame rate. It’s still quite possible that ASW auto-limits it to 45fps though afterwards.
I would generally recommend though to leave FluidSync on until you are sure that a game can sustain 90fps (game fps). Between 45 and 90fps either vorpX or the runtime always create interpolated frames. And 45 stable fps often feel better in this scenario than for example fluctuating 50-75.